CHEMICAL-DYNAMICS OF 1,4,8,11-TETRAAZACYCLOTETRADECANE NICKEL(II) PERCHLORATE WITH SEVERAL SOLVENTS .1. THERMODYNAMICS OF BASE ADDUCT FORMATION

被引：22

作者：

VIGEE, GS ^{[1
]}

WATKINS, CL ^{[1
]}

BOWEN, HF ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,BIRMINGHAM,AL 35294

来源：

INORGANICA CHIMICA ACTA | 1979年 / 35卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)93448-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A solvent adduct study of 1,4,8,11-tetraazacyclotetradecane nickel(II) perchlorate with the coordinating solvents acetonitrile, N,N-dimethylformamide (DMF), methyl sulfoxide (DMSO), and water by optical and nmr techniques is reported. The thermodynamic parameters ΔH°, ΔS°, and Keq for adduct formation are given for each solvent system. At 25 °C, the stability order is found to be DMF > CH3CN > DMSO > H2O. A comparison of the observed stability order and stabilities predicted by single optical measurements and solvent donicity is presented. © 1979.

引用

页码：255 / 259

页数：5

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