MAGNETIC-ORDERING IN COTA2O6 AND NITA2O6

被引:43
作者
KREMER, RK
GREEDAN, JE
机构
[1] MCMASTER UNIV,INST MAT RES,HAMILTON L8S 4M1,ONTARIO,CANADA
[2] MCMASTER UNIV,DEPT CHEM,HAMILTON L8S 4M1,ONTARIO,CANADA
关键词
MAGNETIC MATERIALS - Order-Disorder - NICKEL COMPOUNDS - Magnetic Properties;
D O I
10.1016/0022-4596(88)90149-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Magnetic measurements on CoTa//2O//6 and NiTa//2O//6 are reported. The samples were obtained by a chemical transport reaction using chlorine as the transporting agent. Susceptibility data show, in contrast to former investigations, long-range magnetic ordering at T//c equals 6. 64 K (Co) and 10. 3 K (Ni). Broad maxima in the magnetic susceptibility above T//c are attributed to low-dimensional short-range magnetic ordering. The relevancy of these observations for the chemistry of the title compounds is discussed.
引用
收藏
页码:579 / 582
页数:4
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