ELECTRONIC SPECTRA OF CARBONYL COMPOUNDS .2. SPECTRA AND MOLECULAR ORBITAL CALCULATIONS FOR TYPICAL ACETYL AND BENZOYL SYSTEMS

被引：33
作者：
YATES, K
KLEMENKO, SL
CSIZMADIA, IG
机构：
[1] Department of Chemistry, University of Toronto, Toronto, Ont.
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 04期
关键词：
D O I：
10.1016/0584-8539(69)80051-6
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The electronic and steric effects of a substituent X in typical acetyl (CH3COX) and benzoyl (PhCOX) systems have been investigated experimentally (ultraviolet spectra) and theoretically (LCAO-MO calculations). The good semiquantitative agreement between calculated and observed results (based on a study of twenty-six different carbonyl derivatives) allows some general conclusions to be drawn concerning the effects of substituents on the electronic transitions. © 1969.
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页码：765 / +
页数：1
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