ABSORPTION AND FLUORESCENCE CHARACTERISTICS OF SOME 2-ARYL-BENZOTHIAZOLES AND 2-HETEROARYL-BENZOTHIAZOLES IN DIFFERENT SOLVENTS AND AT VARIOUS PH VALUES

被引：9

作者：

TRALICKULENOVIC, V ^{[1
]}

FISERJAKIC, L ^{[1
]}

LAZAREVIC, Z ^{[1
]}

机构：

[1] UNIV ZAGREB, FAC CHEM ENGN & TECHNOL, HR-10002 ZAGREB, CROATIA

来源：

SPECTROSCOPY LETTERS | 1993年 / 26卷 / 09期

关键词：

BENZOTHIAZOLE; FLUORESCENCE; QUANTUM EFFICIENCY;

D O I：

10.1080/00387019308010775

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The parameters characterizing the absorption and fluorescence of seven 2-substituted benzothiazoles in different solvents and at various acid/base concentrations were studied. It was found that both the kind of substituent and the solvent polarity influenced the changes of the spectral properties of the examined molecules. 2-Aryl substituted benzothiazoles exhibit larger Stokes shifts than 2-heteroaryl derivatives. The linear relationship between solvent polarity and pH values against Stokes shift and fluorescence sensitivity, respectively, was observed. The mostly fluorescent compound was 2-(2-benzofuryl)benzothiazole.

引用

页码：1771 / 1784

页数：14

共 45 条

[1] ABSORPTION AND FLUORESCENCE CHARACTERISTICS OF SOME 2-ARYL-BENZOTHIAZOLES AND 2-HETARYL-BENZOTHIAZOLES
TIMTCHEVA, I
DELIGEORGIEV, T
DYES AND PIGMENTS, 1993, 21 (04) : 293 - 299
[2] Synthesis of 2-aryl-benzothiazoles via Ni-catalyzed coupling of benzothiazoles and aryl sulfamates
Yu, Xiaofeng
Zhang, Zhen
Song, Renyuan
Gou, Liping
Wang, Guangrong
HETEROCYCLIC COMMUNICATIONS, 2020, 26 (01) : 1 - 5
[3] AN IMPROVED METHOD FOR THE PREPARATION OF 2-ARYL-BENZOTHIAZOLES, 2-HETARYL-BENZOTHIAZOLES AND 2-STYRYLBENZOTHIAZOLES
DELIGEORGIEV, TG
DYES AND PIGMENTS, 1990, 12 (04) : 243 - 248
[4] ABSORPTION AND FLUORESCENCE CHARACTERISTICS OF SOME 2-ALKYL-BENZOXAZOLES 2-ARYL-BENZOXAZOLES IN DIFFERENT SOLVENTS AND AT VARIOUS ACID CONCENTRATIONS
DEY, JK
DOGRA, SK
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1990, 29 (12): : 1153 - 1164
[5] Spectral characteristics of 2-aminodiphenylamine in different solvents and at various pH values
Nayaki, SK
Swaminathan, M
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2001, 57 (07) : 1361 - 1367
[6] ELECTRONIC ABSORPTION AND FLUORESCENCE SPECTRAL CHARACTERISTICS AND PROTOTROPIC REACTIONS OF SOME HYDROXY-SUBSTITUTED AND METHOXY-SUBSTITUTED DERIVATIVES OF 2-(2'-HYDROXYPHENYL)BENZOTHIAZOLES
DEY, JK
DOGRA, SK
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1992, 66 (01) : 15 - 31
[7] THE NEAR-ULTRA-VIOLET ABSORPTION SPECTRA OF SOME HETEROCYCLIC COMPOUNDS .2. BENZOTHIAZOLES
CERNIANI, A
PASSERINI, R
JOURNAL OF THE CHEMICAL SOCIETY, 1954, (JUL): : 2261 - 2264
[8] Absorption and fluorescence properties of some substituted 2-furylbenzothiazoles and their vinylogues in various solvents
Tralic-Kulenovic, V
Racanè, L
Karminski-Zamola, G
SPECTROSCOPY LETTERS, 2003, 36 (1-2) : 43 - 50
[9] TBHP/KI-Promoted Annulation of Anilines, Ethers, and Elemental Sulfur: Access to 2-Aryl-, 2-Heteroaryl-, or 2-Alkyl-Substituted Benzothiazoles
Zhang, Jie
Zhao, Xin
Liu, Ping
Sun, Peipei
JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (19): : 12596 - 12605
[10] BENZOTHIAZOLE DERIVATIVES .8. SYNTHESIS OF SOME 2-(4-ALKYL OR ARYL-2-THIAZOLYL)BENZOTHIAZOLES AND 12-(4-ALKYL OR ARYL-2-THIAZOLYLAMINO)-BENZOTHIAZOLES AS POTENTIAL ANTI-INFLAMMATORY AGENTS
SAWHNEY, SN
BANSAL, OP
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1977, 15 (02): : 121 - 124

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