SYNTHESIS AND REACTIVITY OF TRICARBONYL(ETA-5-4-TRIETHYLSILYL-1-METHYLPENTADIENYL)IRON(+1) CATION

被引：24
作者：
DONALDSON, WA
BELL, PT
JIN, MJ
机构：
[1] Department of Chemistry, Marquette University, Milwaukee
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 441卷 / 03期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0022-328X(92)80176-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tricarbonyl(eta5-4-triethylsilyl-1-methylpentadienyl)iron(+1) hexafluorophosphate was prepared by the protonation of psi-endo tricarbonyl(eta4-5-triethylsilyl-3,5-hexadien-2-ol)iron with hexafluorophosphoric acid. The cation reacts with H2O, CH3OH, NaBH3CN, PPh3, Sodium dimethylmalonate and dimethyl cuprate in a regiospecific fashion by nucleophilic attack at Cl. The regioselectivity for nucleophilic attack appears to be predominantly the result of steric control.
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页码：449 / 456
页数：8
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