STRUCTURE OF TRIS(2-MERCAPTOPYRIDINE 1-OXIDO)COBALT(III) ACETONITRILE SOLVATE

被引：23

作者：

HU, YH

WENG, LH

HUANG, LG

CHEN, XT

WU, DX

KANG, BS

机构：

[1] CHINESE ACAD SCI,FUZHOU LAB STRUCT CHEM,FUJIAN 350002,PEOPLES R CHINA

[2] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUJIAN 350002,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270191007473

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Co(C15H12N3O3S3)].C2H3N, M(r) = 478.46, triclinic, P1BAR, a = 9.332 (2), b = 12.726 (3), c = 8.721 (2) angstrom, alpha = 94.01 (2), beta = 94.44 (2), gamma = 75.94 (2)-degrees, V = 1000.2 angstrom 3, Z = 2, D(x) = 1.59 g cm-3, Mo K-alpha (graphite monochromated), lambda = 0.71069 angstrom, mu = 11.8 cm-1, F(000) = 488, T = 296 K, final R = 0.046 for 3731 reflections with I > 3-sigma(I). The three 2-mercaptopyridine 1-oxido ligands with an average bite angle of 88.0-degrees chelate to the cobalt atom via oxygen and sulfur atoms forming a distorted octahedral coordination unit CoO3S3. The average bond distance of Co-S is 2.194 and that of Co-O is 1.933 angstrom.

引用

页码：2655 / 2656

页数：2

共 8 条

[1]

Cromer D.T, 1974, INT TABLES XRAY CRYS, VIV

[2]

FRENZ BA, 1978, COMPUTING CRYSTALLOG

[3] COORDINATION CHEMISTRY OF MICROBIAL IRON TRANSPORT COMPOUNDS .17. PREPARATION AND STRUCTURAL CHARACTERIZATION OF TRIS(N-METHYLTHIOBENZOHYDROXAMATO)COBALT(III), TRIS(N-METHYLTHIOBENZOHYDROXAMATO)CHROMIUM(III), TRIS(N-METHYLTHIOBENZOHYDROXAMATO)IRON(III), AND TRIS(N-METHYLTHIOBENZOHYDROXAMATO)MANGANESE(III) [J].