CHLORYL CATION, CLO2+

被引：43

作者：

CHRISTE, KO

SCHACK, CJ

PILIPOVI.D

SAWODNY, W

机构：

[1] Rocketdyne, Division of North American Rockwell Corporation, Canoga Park

[2] Institut fϋr Anorganische Chemie, Universita, Stuttgart, Germany

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期

关键词：

D O I：

10.1021/ic50081a050

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1:1 adducts ClO2F · AsF5 and ClO2F · BF3 have been investigated. Whereas ClO2F · AsF5 is stable at ambient temperature,the ClO2F · BF3 adduct shows a dissociation pressure of 225 mm at 25°. A pressure-temperature curve gives a heat of reaction of 24.0 kcal mol-1, for the dissociation process: ClO2F · BF3(s)= ClO2F(g) + BF3(g). The X-ray powder patterns of ClO2F · AsF5 and ClF3· AsF6 were recorded and indexed. Infrared and Raman measurements show that ClO2F·AsF6 and ClO3F · BF3 have the ionic structures ClO2+AsF6- and ClO2+BF4-, respectively, in the solid state. All fundamental vibrations were observed and a valence force field was calculated for ClO2+. © 1969, American Chemical Society. All rights reserved.

引用

页码：2489 / &

共 38 条

[1]

BOUGON R, 1967, CR ACAD SCI C CHIM, V265, P179

[2]

CARTER GA, 1968, CHEM COMMUN, P1461

[3]

Christe K. O., 1966, INORG NUCL CHEM LETT, V2, P83

[4] COMPLEX FLUORO CATIONS .3. TETRAFLUORONITROGEN(V) CATION NF4+ . VIBRATIONAL AND FLUORINE-19 NUCLEAR MAGNETIC RESONANCE SPECTRA OF NF4+ASF6- [J].