SURFACE EQUATIONS OF STATE FOR INSOLUBLE MONOLAYERS ON AQUEOUS-SOLUTIONS

被引：15

作者：

MACARTHUR, BW ^{[1
]}

BERG, JC ^{[1
]}

机构：

[1] UNIV WASHINGTON,DEPT CHEM ENGN,SEATTLE,WA 98195

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1979年 / 68卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0021-9797(79)90274-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Surface pressure-area and surface potential-area data are presented for the following systems: myristic acid, oleic acid, ethyl myristate, and ethyl pentadecanoate on aqueous solutions of n-butanol, t-butanol, 1,4-butanediol, glycerol, and d-glucose. The upper and lower limits on compression rate required in each case to assure monolayer uniformity and negligible dissolution are determined. The surface equations of state proposed by Lim and Berg [J. Colloid Interface Sci. 51, 162 (1975)] produce excellent fits of the II-α data and may be used to extrapolate such data outside the accessible range of solute concentrations. © 1979.

引用

页码：201 / 213

页数：13

共 11 条

[1]

ADAM NK, 1939, P ROY SOC LOND A MAT, V170, P485

[2]

BERG JC, 1972, RECENT DEV SEPARATIO, V2, P1

[3] The thermodynamics of the surfaces of solution [J].