PARTITION-COEFFICIENTS OF BENZENE-DERIVATIVES IN AQUEOUS 2-PHASE SYSTEMS CONTAINING POLYETHYLENE-GLYCOL

被引：7

作者：

MISHIMA, K ^{[1
]}

MORII, S ^{[1
]}

NAGAYASU, S ^{[1
]}

EYA, H ^{[1
]}

NAGATANI, M ^{[1
]}

ARAI, Y ^{[1
]}

机构：

[1] KYUSHU UNIV,DEPT CHEM ENGN,FUKUOKA 812,JAPAN

来源：

KAGAKU KOGAKU RONBUNSHU | 1993年 / 19卷 / 06期

关键词：

PHASE EQUILIBRIUM; AQUEOUS; 2; PHASE; PARTITION COEFFICIENT; POLYETHYLENE GLYCOL; DIPOTASSIUM HYDROGENPHOSPHATE; DEXTRAN; AMMONIUM SULFATE; BENZENE DERIVATIVE; OSMOTIC VIRIAL EQUATION; MOLECULAR CONNECTIVITY INDEX;

D O I：

10.1252/kakoronbunshu.19.1171

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The liquid-liquid equilibria of the aqueous two-phase systems consisting of polyethylene glycol (M(w) = 7,500) (1)-dipotassium hydrogenphosphate (2)-water(3), polyethylene glycol(l)- ammonium sulfate(2)- water(3) and polyethylene glycol(1)- dextran (M(w) = 515,000, M(n) = 195,300) (2) - water (3) were measured at 25-degrees-C. The partition coefficients of 15 benzene derivatives in these aqueous two-phase systems were also determined at 25-degrees-C. Further, the osmotic virial equation was used to correlate the liquid-liquid equilibria of the aqueous two-phase systems and the partition coefficients of 15 benzene derivatives. An estimation of the partition coefficients was attempted by using molecular connectivity indices.

引用

页码：1171 / 1178

页数：8

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