N-NITROSOHYDROXYLAMINES .3. REACTION OF N,O-DIBENZYL-N-NITROSOHYDROXYLAMINES WITH ACETIC-ANHYDRIDE

被引：6

作者：

KANO, K ^{[1
]}

ANSELME, JP ^{[1
]}

机构：

[1] UNIV MASSACHUSETTS,DEPT CHEM,HARBOR CAMPUS,BOSTON,MA 02125

来源：

TETRAHEDRON | 1993年 / 49卷 / 42期

关键词：

D O I：

10.1016/S0040-4020(01)80214-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The major path of the reaction of N,O-dibenzyl-N-nitrosohydroxylamines (3) with acetic anhydride appears to proceed by initial radical cleavage of the N-N bond with loss of nitric oxide. The formation of the main products (5) may be rationalized by subsequent transformation of the resulting hydroxylamino radicals.

引用

页码：9453 / 9458

页数：6