APPLICATION OF LINNETT ELECTRONIC THEORY TO ORGANIC CHEMISTRY .2. INTRODUCTION

被引：29
作者：
FIRESTONE, RA
机构：
[1] Merck Sharp & Dohme Research Laboratories, Division of Merck & Co., Inc., Rahway, New Jersey
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 09期
关键词：
D O I：
10.1021/jo01261a029
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The double-quartet theory of Linnett is shown to account for a wide variety of typical organic structural phenomena. The concept of L strain, a unique corollary of the Linnett theory, is discussed and put on a semiquantitative basis. Examples of problems in geometry, stabilization, hyperconjugation, and configurational inversion are provided from among the classes alkanes, alkenes, alkynes, amines, carbanions, carbonium ions, radicals, and carbenes, and certain predictions are made. © 1969, American Chemical Society. All rights reserved.
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页码：2621 / +
页数：1
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