SELECTION-RULES IN RESONANT 4F PHOTOEMISSION FOR RARE-EARTHS

被引:8
|
作者
KAI, M [1 ]
TANAKA, A [1 ]
JO, T [1 ]
机构
[1] HIROSHIMA UNIV, FAC SCI, DEPT MAT SCI, HIGASHIHIROSHIMA 739, JAPAN
关键词
RESONANT PHOTOEMISSION; RARE EARTHS; SELECTION RULES; MULTIPLET STRUCTURES;
D O I
10.1143/JPSJ.64.2356
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The difference in 4f photoemission spectrum (PES) for rare earths (RE) Nd, Gd and Dy under off-resonance and various on-resonance conditions near the 3d core threshold is discussed on the basis of an ionic model assuming trivalence. For the resonant process passing through a higher-energy intermediate state of both 3d(5/2) and 3d(3/2) regions, the spectral intensity in higher (lower) binding energy multiplets of 4f PES is shown to be enhanced (suppressed) compared with off-resonance spectra. This tendency is especially remarkable for Gd and heavier rare earths. An intuitive interpretation for this tendency is presented and a control of photoexcitation by tuning photon energy, which may be compared to that using a polarized photon, is shown to be feasible.
引用
收藏
页码:2356 / 2359
页数:4
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