REAGENT CONTROL IN THE ALDOL ADDITION-REACTION OF CHIRAL BORON ENOLATES WITH CHIRAL ALDEHYDES

被引：14
作者：
GENNARI, C
MORESCA, D
VULPETTI, A
PAIN, G
机构：
[1] Dip. di Chimica Organica e Industriale, Universita' di Milano, Centro CNR (Sost.Org.Nat.), 20133 Milano
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 26期
关键词：
D O I：
10.1016/S0040-4039(00)60746-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Boron enolates bearing menthone-derived chiral ligands are capable of fair to excellent diastereocontrol in their reactions with chiral aldehydes. Thioester-derived (better than ketone derived) enolates are able to control aldol stereochemistry irrespective of the aldehyde preferences.
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收藏
页码：4623 / 4626
页数：4
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