Boron removal from water and wastewater using new polystyrene-based resin grafted with glycidol

被引：31

作者：

Kluczka, Joanna ^{[1
]}

Korolewicz, Teofil ^{[1
]}

Zolotajkin, Maria ^{[1
]}

Adamek, Jakub ^{[1
]}

机构：

[1] Silesian Tech Univ, Fac Chem, B Krzywoustego 6, PL-44100 Gliwice, Poland

来源：

WATER RESOURCES AND INDUSTRY | 2015年 / 11卷 / 46-57期

关键词：

Boron removal; Glycidol; Resin; Sorption isotherms; Kinetics; Thermodynamics;

D O I：

10.1016/j.wri.2015.05.001

中图分类号：

TV21 [水资源调查与水利规划];

学科分类号：

081501 ;

摘要：

A divinylbenzene cross linked polystyrene resin with amine functional groups (Purolite A170) was grafted with glycidol and characterized as a novel sorbent, GLY-resin, for the oxoborate removal from model solutions and post crystallization lye. The sorption behavior of GLYresin was investigated using a batch system. The results showed that the sorption was maximal at pH=9.5. The equilibrium was achieved after 24 h. Calculations based on Lan;,Ymuir model show the monolayer sorption capaciLy q(m)=13 mg/g and the fitted experimental clata chemisorption as a dominating mechanism of boron sorption on GLYresin. Boron removal from the solution containing 5 mg B/L and post:crystallization lye having a 9.1 mg B/L was 99% and 80% respectively. The thermodynamic calculations indicated the spontaneous and endothermic nature of the sorption process. The pseudo-secondorder model adequately described the boron sorption On GLY-resin. Sorption desorption efficiency was 100%, which means the boron sorption at next cycle did not decrease. (C) 2015 The Authors. Published by Elsevier BA/.

引用

页码：46 / 57

页数：12

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