AN ELECTRON SPIN RESONANCE STUDY OF SOME ALIPHATIC AND ALICYCLIC ETHER RADICALS

被引：46

作者：

HUDSON, A

ROOT, KDJ

机构：

[1] School of Molecular Sciences, The University of Sussex, Brighton

来源：

TETRAHEDRON | 1969年 / 25卷 / 21期

关键词：

D O I：

10.1016/0040-4020(69)80053-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of photochemically generated t-butoxyl radicals with a wide range of aliphatic and alicyclic ethers have been investigated by ESR. The spectra of several new radicals are described and the identity of the radicals is compared with the species formed by other oxidizing systems. Restricted rotation giving rise to line-width alternation has been observed in the spectrum of CH2OCH3 formed from dimethylether. © 1969.

引用

页码：5311 / &

共 20 条

[1] ELECTRON PARAMAGNETIC RESONANCE OF T-BUTOXY RADICAL REACTIONS WITH ALCOHOLS [J].

ADAMS, JQ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (20) :5363-&

[2] ELECTRON SPIN RESONANCE SPECTRA OF TRIMETHYLSILYL TRIMETHYLGERMYL AND RELATED FREE RADICALS IN SOLUTION [J].

BENNETT, SW ;

EABORN, C ;

HUDSON, A ;

HUSSAIN, HA ;

JACKSON, RA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1969, 16 (02) :P36-&

[3] ELECTRON SPIN RESONANCE STUDIES OF OXIDATION .3. SOME ALICYCLIC COMPOUNDS [J].

DIXON, WT ;

NORMAN, ROC .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (DEC) :4850-&

[4] ELECTRON SPIN RESONANCE STUDIES OF OXIDATION .2. ALIPHATIC ACIDS + SUBSTITUTED ACIDS [J].

DIXON, WT ;

NORMAN, ROC ;

BULEY, AL .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (OCT) :3625-&

[5] ELECTRON SPIN RESONANCE STUDIES OF TRANSIENT ALKYL RADICALS [J].

FESSENDEN, RW ;

SCHULER, RH .

JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (09) :2147-&

[6] SECOND-ORDER SPLITTINGS IN ESR SPECTRA OF ORGANIC RADICALS [J].

FESSENDEN, RW .

JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (04) :747-&

[7] ELECTRON SPIN RESONANCE AND ELECTRONIC STRUCTURE OF RCHOR' ETHER RADICALS [J].

GRIFFITH, OH .

JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (08) :2651-&

[8] ELECTRON SPIN RESONANCE SPECTRUM OF TRICHLOROMETHYL RADICAL IN SOLUTION [J].

HUDSON, A ;

HUSSAIN, HA .

MOLECULAR PHYSICS, 1969, 16 (02) :199-&

[9] ELECTRON RESONANCE OF 2-THENYL AND 3-THENYL RADICALS - INEQUIVALENCE OF METHYLENE PROTONS [J].

HUDSON, A ;

HUSSAIN, HA ;

LEWIS, JWE .

MOLECULAR PHYSICS, 1969, 16 (05) :519-&

[10]

HUDSON A, IN PRESS

← 1 2 →