Crystal structure of 4-(trimethylgermyl) benzoic acid

被引：0

作者：

Knauer, Lena ^{[1
]}

Barth, Eva R. ^{[1
]}

Golz, Christopher ^{[1
]}

Strohmann, Carsten ^{[1
]}

机构：

[1] Tech Univ Dortmund, Fak Chem & Chem Biol, Otto Hahn Str 6, D-44227 Dortmund, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; 4-(trimethylgermyl) benzoic acid; germanium; hydrogen bonding;

D O I：

10.1107/S2056989015009160

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ge(CH3)(3)(C7H5O2)], was obtained as a by-product in the synthesis of the corresponding aldehyde. Two slightly different molecules are present in the asymmetric unit. In both molecules, the geometry of the aromatic ring plane is distorted by varying intensities. Additionally, the Ge atoms deviate from the mean aromatic ring planes. Whereas the distance of the Ge atom to the ring plane is only 0.101 (4) angstrom in the first molecule, this distance is increased to 0.210 (4) angstrom in the second. In the crystal structure, centrosymmetric O-H center dot center dot center dot O hydrogen-bonded dimers are formed. The title compound is isostructural with the Si analogue [Haberecht et al. (2004). Acta Cryst. E60, o329-0330].

引用

页码：687 / +

页数：9

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