THE ROLE OF RADICALS IN THE BELOUSOV - ZHABOTINSKY REACTION

被引：21
作者：
FORSTERLING, HD
MURANYI, S
NOSZTICZIUS, Z
机构：
[1] Fachbereich Physikalische Chemie, Philipps-Universität Marburg, Marburg
[2] Department of Physics, University of Texas at Austin, Austin
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1990年 / 42卷 / 02期
关键词：
D O I：
10.1007/BF02065357
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new theory of the Belousov-Zhabotinsky (BZ) reaction, the Radicalator model, is presented. This model is based on a negative feedback loop involving a fast reaction between malonyl and bromine dioxide radicals. Experimental evidence for the validity of the model is given for BZ systems in 3 M and 1 M sulfuric acid solution. © 1990 Akadémiai Kiadó.
引用
收藏
页码：217 / 226
页数：10
相关论文
共 15 条
[1]  
Field R.J., Koros E., Noyes R.M., J. Am. Chem. Soc., 94, (1972)
[2]  
Oscillations and Traveling Waves in Chemical Systems, (1985)
[3]  
Ruoff P., Varga M., Koros E., Acc. Chem. Res., 21, (1988)
[4]  
Forsterling H.D., Schreiber H., Zittlau W., Z. Naturforsch., 33 a, (1978)
[5]  
Forsterling H.D., Lamberz H., Schreiber H., Z. Naturforsch., 35 a, (1980)
[6]  
Forsterling H.D., Lamberz H.J., Schreiber H., Z. Naturforsch., 35 a, (1980)
[7]  
Forsterling H.D., Lamberz H.J., Schreiber H., Z. Naturforsch., 38 a, (1983)
[8]  
Noszticzius Z., Noszticzius E., Schelly Z.A., J. Am. Chem. Soc., 104, (1982)
[9]  
Field R.J., Forsterling H.D., J. Phys. Chem., 90, (1986)
[10]  
Noszticzius Z., Gaspar V., Forsterling H.D., J. Am. Chem. Soc., 107, (1985)
12