DETERMINATION OF STATIC DIELECTRIC CONSTANT-TEMPERATURE DENSITY SURFACES OF A STOCKMAYER FLUID BY PERTURBATION-THEORY

被引：32

作者：

GOLDMAN, S

机构：

[1] Guelph-Waterloo Centre for Graduate Work in Chemistry, Guelph Campus, University of Guelph, Guelph, ON

来源：

MOLECULAR PHYSICS | 1990年 / 71卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1080/00268979000101931

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Second-order perturbation theory is applied to a Stockmayer fluid to obtain its static dielectric constant over a range of temperatures, densities and dipole moments. A discrepancy in the literature, associated with this calculation, is identified and explained. An explanation is also provided for the fact that the theory predicts the dielectric constant accurately for low to moderately high dipole moments, while it is very inaccurate in its prediction of angular structure. © 1990 Taylor and Francis Ltd.

引用

页码：491 / 507

页数：17

共 20 条

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