LEWIS-BASE ADDUCTS OF MAIN GROUP 1 METAL(I) COMPOUNDS .14. SYNTHESIS AND CRYSTAL-STRUCTURE OF A 1 - 1 LITHIUM(I) CHLORIDE SULFOLANE ADDUCT

被引：8
作者：
HARVEY, S
SKELTON, BW
WHITE, AH
机构：
[1] Department of Physical and Inorganic Chemistry, University of Western Australia
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1991年 / 44卷 / 02期
关键词：
D O I：
10.1071/CH9910309
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystallization of anhydrous lithium(I) chloride from dry sulfolane yields a colourless crystalline 1:1 adduct, characterized by analysis and a single-crystal X-ray structure determination. Crystals are orthorhombic, Pna2(1), a 10.940(3), b 9.611(4), c 6.576(3) angstrom, Z = 4 formula units; R was 0.033 for 869 independent 'observed' reflections. The structure is an infinite polymer containing four-coordinate (LiCl2O2) lithium, bridged by Li-Cl interactions and O,O' sulfolanes. Li-Cl, Cl' are 2.375(8), 2.309(7), and Li-O, O' 2.016(7), 1.991(6) angstrom.
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页码：309 / 312
页数：4
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