XPS INVESTIGATIONS OF ACID-BASE INTERACTIONS IN ADHESION .5. THE DETERMINATION OF ACID-BASE PROPERTIES OF POLYMER SURFACES - PRESENT STATUS AND FUTURE-PROSPECTS

被引:7
作者
WATTS, JF [1 ]
CHEHIMI, MM [1 ]
机构
[1] UNIV PARIS 07,CNRS,INST TOPOL & DYNAM SYST,F-75005 PARIS,FRANCE
关键词
POLYMER SURFACES; ACID-BASE PROPERTIES; X-RAY PHOTOELECTRON SPECTROSCOPY;
D O I
10.1016/0143-7496(95)98743-6
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The use of a polymer swelling method, in conjunction with X-ray photoelectron spectroscopy, is shown to provide an attractive method for the determination of the acid-base properties of polymers in the solid state. This method is reviewed and examples of the use of trichloromethane as a molecular probe are given. It is shown how, by the study of polymer swelling by two solvents of known acid-base properties, Drago's E and C parameters for the candidate polymer can be determined. Examples are provided of the use of this method on a homopolymer and the surface treatment of polypropylene.
引用
收藏
页码:91 / 94
页数:4
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