Solvent-free synthesis of clathrasils using metal-organic complexes as structure-directing agents

被引：14

作者：

vandeGoor, G

Lindlar, B

Felsche, J

Behrens, P

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,D-80333 MUNICH,GERMANY

[2] UNIV KONSTANZ,FAK CHEM,D-78434 CONSTANCE,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期

关键词：

D O I：

10.1039/C39950002559

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two metal-organic complex salts [Co(C(5)H(4)Me)(2)]PF6 and [Fe(C6H6)(C5H5)]PF6 are tested as structure-directing agents in the synthesis of pure silica zeotype materials and give the clathrasil structure dodecasil-1H only in the solvent-free synthesis system SiO2-NH4F-metal complex.

引用

页码：2559 / 2561

页数：3