QUANTUM-MECHANICAL EFFECTS IN THE 3-DIMENSIONAL LOW-ENERGY D+H2-]HD+H REACTION

被引：8

作者：

KORNWEITZ, H ^{[1
]}

PERSKY, A ^{[1
]}

BAER, M ^{[1
]}

机构：

[1] SOREQ NUCL RES CTR,DEPT PHYS & APPL MATH,IL-70600 YAVNE,ISRAEL

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 08期

关键词：

D O I：

10.1063/1.460487

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work possible quantum mechanical effects for the three dimensional reactive D + H2 --> HD + H reaction are discussed. The study is carried out by comparing quantum mechanical and quasiclassical backscattered differential cross sections as a function of collision energy. A strong quantum effect is detected for the upsilon' = 0- > upsilon' = 0 transition in the energy range around E(tr) = 13 kcal/mol.

引用

页码：5524 / 5529

页数：6

共 34 条

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