FORMATION OF [M-C2H4]+. IN O-D1-BUTYRIC ACID

被引：29
作者：
FAIRWEATHER, RB
MCLAFFERTY, FW
机构：
[1] Department of Chemistry, Purdue University, Lafayette, Indiana
[2] Department of Chemistry, University of Connecticut, Storrs, Connecticut
[3] Department of Chemistry, Cornell University, Ithaca, New York
来源：
ORGANIC MASS SPECTROMETRY | 1969年 / 2卷 / 07期
关键词：
D O I：
10.1002/oms.1210020710
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The mass spectrum of CH3CH2CH2COOD shows no observable loss of C2H3D. This indicates for this compound that either the McLafferty rearrangement is concerted, or that the second step (olefin loss) is very fast in comparison to the reverse transfer of hydrogen back to the methylene radical. Copyright © 1969 John Wiley & Sons, Ltd.
引用
收藏
页码：755 / +
页数：1
相关论文
共 13 条
[1]  
BEYNON JH, 1968, ADV MASS SPECTROM, V4, P123
[2]   ELECTRONIC STRUCTURE OF 6-MEMBERED CYCLIC TRANSITION STATE IN SOME GAMMA-HYDROGEN REARRANGEMENTS [J].
BOER, FP ;
SHANNON, TW ;
MCLAFFER.FW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (26) :7239-&
[3]  
BUDZIKIEWICZ H, 1967, MASS SPECTROMETRY OR, P155
[4]   MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .144. UNUSUAL FRAGMENTATIONS IN LOW-VOLTAGE SPECTRA OF ALIPHATIC KETONES [J].
CARPENTER, W ;
DUFFIELD, AM ;
DJERASSI, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (01) :160-+
[5]   DEUTERIUM ISOTOPE EFFECTS IN PHOTOCHEMISTRY OF 2-HEXANONE [J].
COULSON, DR ;
YANG, NC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (19) :4511-&
[6]   A GENERALIZED MECHANISM FOR MASS SPECTRAL REACTIONS [J].
MCLAFFERTY, FW .
CHEMICAL COMMUNICATIONS, 1966, (03) :78-+
[7]   MASS SPECTROMETRIC ANALYSIS - BROAD APPLICABILITY TO CHEMICAL RESEARCH [J].
MCLAFFERTY, FW .
ANALYTICAL CHEMISTRY, 1956, 28 (03) :306-316
[8]   HYDROGEN REARRANGEMENTS IN SOME UNSATURATED IONS [J].
MILLARD, BJ ;
SHAW, DF .
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1966, (07) :664-&
[9]   MASS SPECTROMETRY OF ARALKYL COMPOUNDS WITH A FUNCTIONAL GROUP .6. MASS SPECTRA OF 1-PHENYLETHANOL-1,2-PHENYLETHANOL-1 AND 1-PHENYLPROPANOL-2 [J].
NIBBERING, NM ;
DEBOER, TJ .
ORGANIC MASS SPECTROMETRY, 1968, 1 (03) :365-+
[10]   MASS SPECTROMETRY OF ARALKYL COMPOUNDS WITH A FUNCTIONAL GROUP .4. SPECIFIC EXCHANGE BETWEEN ALPHA- AND ORTHO-HYDROGEN ATOMS IN MOLECULAR ION OF GAMMA-PHENYLPROPYLBROMIDE [J].
NIBBERING, NM ;
DEBOER, TJ .
TETRAHEDRON, 1968, 24 (03) :1427-+
12