(NALI)-LI-7 1 (1)PI(B) ELECTRONIC-STATE LAMBDA-DOUBLING ANALYSIS

被引:3
作者
FELLOWS, CE [1 ]
GUTTERRES, RF [1 ]
TAVARES, AD [1 ]
机构
[1] UNIV ESTADO RIO DE JANEIRO,DEPT ELETRON QUANT,BR-20550 MARACANA,RJ,BRAZIL
关键词
D O I
10.1016/0009-2614(95)00242-V
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lambda-doubling for a particular vibrational energy level of the (NaLi)-Li-7 1 (1) Pi(B) electronic state is calculated using a simple theory. This 1 (1) Pi(B) state is strongly perturbed by the 3 (1) Sigma(+)(C) electronic state so that the Lambda-doubling constant cannot be obtained by a direct reduction of the difference between e and f levels as a function of J(J + 1). A comparison between experimental data and values obtained in this simple theory shows reasonable agreement.
引用
收藏
页码:538 / 542
页数:5
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