Diaquabis(cinnamato-kappa O-2,O ')cadmium

被引:1
作者
Chooset, Sirinart [1 ]
Cunningham, Bryan [2 ]
Kantacha, Anob [3 ]
Zeller, Matthias [2 ]
Wongnawa, Sumpun [1 ]
机构
[1] Prince Songkla Univ, Fac Sci, Dept Chem, Hat Yai 90112, Songkhla, Thailand
[2] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
[3] Thaksin Univ, Fac Sci, Dept Chem, Patthalung 93110, Thailand
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词
Data-to-parameter ratio = 16.9; Mean σ(C-C) = 0.005 Å; R factor = 0.020; Single-crystal X-ray study; T = 100 K; wR factor = 0.046;
D O I
10.1107/S160053681400364X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [Cd(C9H7O2)(2)(H2O)(2)], was obtained as an unintended product of the reaction of cadmium nitrate with hexamethylenetetramine and cinnamic acid. The Cd-II ion lies on a twofold rotation axis and is coordinated in a slightly distorted trigonal-prismatic environment. In the crystal, the V-shaped molecules are arranged in an interlocking fashion along [ 010] and O-H center dot center dot center dot O hydrogen bonds link the molecules, forming a two-dimensional network parallel to (001).
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页码:M106 / +
页数:11
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