PHOTOCATALYSIS OF THE HOMOGENEOUS WATER-GAS SHIFT REACTION UNDER AMBIENT CONDITIONS BY CATIONIC IRIDIUM(III) COMPLEXES

被引：56

作者：

ZIESSEL, R

机构：

[1] Ecole Européenne des Hautes Etudes des Industries Chimiques de Strasbourg, IPCMS/GMI, Strasbourg, F-67 008, 1, rue Blaise Pascal

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 07期

关键词：

D O I：

10.1002/anie.199108441

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first water-gas process catalyzed by Ir complexes of type 1 is characterized by high efficiency and extremely mild conditions. Substitution in the 4,4' position of the bipyridine ligand by electron-withdrawing groups enhances the catalytic activity, since the activation energy of the rate-determing step is halved.

引用

页码：844 / 847

页数：4

共 31 条

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