REACTION OF PENTAFLUORONITROSOBENZENE WITH [OS3H(MU-H)(CO)10(MPH3)] (M=P, AS, SB) - SYNTHESIS AND X-RAY STRUCTURE OF [OS3(MU-H)(CO)10(PPH3)(ONC6F4O)]

被引：3

作者：

ANG, HG

KWIK, WL

ONG, KK

机构：

[1] Department of Chemistry, National University of Singapore, Singapore, 0511, Lower Kent Ridge Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 474卷 / 1-2期

关键词：

OSMIUM; SYNTHESIS;

D O I：

10.1016/0022-328X(94)84059-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pentafluoronitrosobenzene C6F5NO has been shown from infrared spectral, F-19 NMR spectral and single-crystal X-ray diffraction studies to undergo oxidation at the para-position upon reaction with [Os3H(mu-H)(CO)10(PPh3)] to afford [Os3(mu-H)(CO)10(PPh3)(ONC6F4O)](I). The arsenic- and stibine- analogues of I ([Os3(mu-H)(CO)10(MPh3)(ONC6F4O)) (M = As, Sb)) were also isolated.

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页码：149 / 152

页数：4

相关论文

共 12 条

[1] TRIOSMIUM CLUSTER COMPOUNDS CONTAINING ISOCYANIDE AND HYDRIDE LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURE OF (MU-H)(MU-ETA-1-C=N(H)(TERT-C4H9))OS3(CO)10 [J].

ADAMS, RD ;

GOLEMBESKI, NM .

INORGANIC CHEMISTRY, 1979, 18 (08) :2255-2258

[2] HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY OF SOME N-PENTAFLUOROPHENYL DERIVATIVES [J].

ANG, HG ;

KWIK, WL ;

ONG, KK .

JOURNAL OF FLUORINE CHEMISTRY, 1990, 49 (03) :321-330

[3] REACTION OF PENTAFLUORONITROSOBENZENE WITH [OS3(CO)11(CH3CN)] AND HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC SEPARATION OF [OS3(CO)11(MU-ONC6F5)], [OS3(CO)9(MU-3-NC6F5)2], [OS3(CO)11(CH3CN)] AND OS3(CO)12 [J].

ANG, HG ;

KWIK, WL ;

ONG, KK .

JOURNAL OF FLUORINE CHEMISTRY, 1993, 60 (01) :43-48

[4] THE REACTION OF PENTAFLUORONITROSOBENZENE WITH OS3(CO)12 - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [OS3(CO)9(MU-3-NC6F5)2] [J].

ANG, HG ;

KWIK, WL ;

ONG, KK .

JOURNAL OF FLUORINE CHEMISTRY, 1992, 56 (01) :45-49

[5]

BOSCHKE FL, 1983, TABLES SPECTRAL DATA, P1110

[6] STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES .3. CRYSTAL-STRUCTURE AND MOLECULAR-GEOMETRY OF H2OS3(CO)10(PPH3), INCLUDING DIRECT LOCATION OF BOTH TERMINAL AND MU2-BRIDGING HYDRIDE LIGANDS [J].

CHURCHILL, MR ;

DEBOER, BG .

INORGANIC CHEMISTRY, 1977, 16 (09) :2397-2403

[7] NEUTRON-DIFFRACTION STRUCTURE-ANALYSIS OF [(MU-H)(MU-NCHCF3)OS3(CO)10] AT 20 K [J].

DAWOODI, Z ;

MAYS, MJ ;

ORPEN, AG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 219 (02) :251-257

[8]

DEAN JA, 1987, HDB ORGANIC CHEM, P3

[9]

Dolphin D., 1977, TABULATION INFRARED, P178

[10]

GLADFELTER WL, 1985, ADV ORGANOMET CHEM, V24, P41