FACILE REGENERATION OF CARBONYL-COMPOUNDS FROM 1,3-DITHIANE 1-OXIDES VIA 1-ETHOXY-1,3-DITHIANIUM SALTS

被引：5

作者：

STAHL, I ^{[1
]}

APEL, J ^{[1
]}

MANSKE, R ^{[1
]}

GOSSELCK, J ^{[1
]}

机构：

[1] UNIV GESAMTHSCH KASSEL,BEREICH ORGAN CHEM,D-3500 KASSEL,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 02期

关键词：

D O I：

10.1002/anie.197901651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Liberation of aldehydes RCHO from dithiane oxides 1 can be accomplished by transformation into the salts 3 and their cleavage with water. The reaction sequence (1)→(3) → RCHO is milder than the usual cleavage of 1 with acid. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：165 / 166

页数：2

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