TRANSITION-METAL ION COMPLEXES OF 2-METHYLSULFINYLPYRIDINE N-OXIDE

被引：6
作者：
CHARTIER, LH
KOHRMAN, RE
WEST, DX
机构：
[1] ILLINOIS STATE UNIV,DEPT CHEM,NORMAL,IL 61761
[2] CENT MICHIGAN UNIV,DEPT CHEM,MT PLEASANT,MI 48859
来源：
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 05期
关键词：
D O I：
10.1016/0022-1902(79)80350-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Transition metal ion complexes in which 2-methylsulfinylpyridine N-oxide acts as a bidentate ligand have been prepared and characterized by molar conductivity measurements as well as IR and electronic spectra. Crystal field parameters are calculated for the Cr(III), Co(II) and Ni(II) solids based on octahedral symmetry from solid state spectra. Optical electronegativity calculations indicate that the charge transfer bands are metal-ligand in nature. © 1979.
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页码：657 / 661
页数：5
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