PERFECTLY ALTERNATING ETHYLENE-CARBON MONOXIDE COPOLYMERS - STRUCTURE AND MORPHOLOGY OF EPITAXIALLY GROWN CRYSTALS

被引：16
|
作者：
GRAYER, V
LOMMERTS, BJ
SMITH, P
LOTZ, B
WITTMANN, JC
机构：
[1] CNRS,INST CHARLES SADRON,F-67083 STRASBOURG,FRANCE
[2] AKZO CORP,CENT RES LABS,6800 SB ARNHEM,NETHERLANDS
[3] UNIAX CORP,SANTA BARBARA,CA 93111
来源：
POLYMER | 1995年 / 36卷 / 09期
关键词：
ALTERNATING COPOLYMER; CRYSTALS; MORPHOLOGY;
D O I：
10.1016/0032-3861(95)90940-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Epitaxial growth of the perfectly alternating ethylene-carbon monoxide copolymer (POK) has been successfully achieved using hydroquinone, first as a solvent in its liquid state, and then as a substrate in its crystallized form. Mono-oriented POK domains grow directly in the alpha crystal form. The polymer chain axis lies parallel to the substrate surface and each domain is composed of a stack of lamellae standing edgewise; the contact plane with the substrate is the crystallographically dense (100) plane.
引用
收藏
页码：1915 / 1918
页数：4
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