SATURATED PYRROLIZIDINE DIOLS .3. A PARTIAL SYNTHESIS OF TURNEFORCIDINE

被引：15
作者：
AASEN, AJ
CULVENOR, CC
机构：
[1] Division of Applied Chemistry, CSIRO, Chemical Research Laboratories, Melbourne, VIC, 3001
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 12期
关键词：
D O I：
10.1071/CH9692657
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Turneforcidine has been prepared by the oxidation of methyl 7α-hydroxy-8α-pyrrolizidine-1α-carboxylate to the 7-keto compound and stepwise reduction with hydrogen/platinum and lithium aluminium hydride. 7β-Hydroxy-8α-pyrrolizidine-1β-carboxylic acid is not epimerized by alkali but converted into the stable γ-lactone (VI). © 1969, CSIRO. All rights reserved.
引用
收藏
页码：2657 / &
相关论文
共 6 条
1