SATURATED PYRROLIZIDINE DIOLS .3. A PARTIAL SYNTHESIS OF TURNEFORCIDINE

被引：15

作者：

AASEN, AJ

CULVENOR, CC

机构：

[1] Division of Applied Chemistry, CSIRO, Chemical Research Laboratories, Melbourne, VIC, 3001

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 12期

关键词：

D O I：

10.1071/CH9692657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Turneforcidine has been prepared by the oxidation of methyl 7α-hydroxy-8α-pyrrolizidine-1α-carboxylate to the 7-keto compound and stepwise reduction with hydrogen/platinum and lithium aluminium hydride. 7β-Hydroxy-8α-pyrrolizidine-1β-carboxylic acid is not epimerized by alkali but converted into the stable γ-lactone (VI). © 1969, CSIRO. All rights reserved.

引用

页码：2657 / &

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