REACTION-MECHANISM OF HYDROCONDENSATION OF CARBON-MONOXIDE

被引：0
作者：
GHAZI, M
BARRAULT, J
机构：
来源：
BULLETIN DES SOCIETES CHIMIQUES BELGES | 1993年 / 102卷 / 02期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this work, a reaction mechanism for oxides hydrocondensation of carbon monoxide on nickel-molybdenum catalyst is proposed. The formation of higher alcohols may occur by a CO insertion into a growing carbon-carbon chain whereas methanol may be formed from CO via formyl or formate species. Hydrocarbon formation may result from superficial ''CH(x)'' species hydrogenation.
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页码：123 / 128
页数：6
相关论文
共 30 条
[11]  
DELUZARCHE A, 1977, TETRAHEDRON LETT, P797
[12]  
GHAZI M, 1990, RECL TRAV CHIM PAY B, V109, P332
[13]  
GHAZI M, 1991, RECL TRAV CHIM PAY B, V110, P19
[14]  
GHAZI M, 1988, THESIS POITIERS
[15]   MECHANISM OF FISCHER TROPSCH SYNTHESIS - CH2-POLYMERIZATION VERSUS CO INSERTION [J].
HENRICIOLIVE, G ;
OLIVE, S .
JOURNAL OF MOLECULAR CATALYSIS, 1982, 16 (01) :111-115
[16]   FISCHER-TROPSCH SYNTHESIS - MOLECULAR-WEIGHT DISTRIBUTION OF PRIMARY PRODUCTS AND REACTION-MECHANISM [J].
HENRICIOLIVE, G ;
OLIVE, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (03) :136-141
[17]  
HENRICIOLIVE G, 1983, J MOL CATAL, V18, P367, DOI 10.1016/S0304-5102(83)80009-1
[18]   HYDROGENATION OF CARBON-MONOXIDE OVER VANADIUM OXIDE-PROMOTED RHODIUM CATALYSTS [J].
KIP, BJ ;
SMEETS, PAT ;
VANGRONDELLE, J ;
PRINS, R .
APPLIED CATALYSIS, 1987, 33 (01) :181-208
[19]   METHANOL SYNTHESIS [J].
KLIER, K .
ADVANCES IN CATALYSIS, 1982, 31 :243-313
[20]  
MAKAMBO L, 1984, 8TH P INT C CAT BERL, V2, P207
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