REACTION-MECHANISM OF HYDROCONDENSATION OF CARBON-MONOXIDE

被引：0

作者：

GHAZI, M

BARRAULT, J

机构：

来源：

BULLETIN DES SOCIETES CHIMIQUES BELGES | 1993年 / 102卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, a reaction mechanism for oxides hydrocondensation of carbon monoxide on nickel-molybdenum catalyst is proposed. The formation of higher alcohols may occur by a CO insertion into a growing carbon-carbon chain whereas methanol may be formed from CO via formyl or formate species. Hydrocarbon formation may result from superficial ''CH(x)'' species hydrogenation.

引用

页码：123 / 128

页数：6

共 30 条

[1]

Bart J. C. J., 1987, CATAL TODAY, V2, P1

[2]

BHAZI M, 1983, THESIS POITIERS

[3]

BHORE NA, 1988, 9TH P INT C CAT CALG, V2, P594

[4] ON THE ACTIVITY OF FISCHER-TROPSCH AND METHANATION CATALYSTS - A STUDY UTILIZING ISOTOPIC TRANSIENTS [J].