DIMERIZATION OF THE STELLATED OCTAHEDRAL UNIT CO6S8P6 - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [CO12(MU-3-S)14(MU-4-S)2(PET3)10][TCNQ]2, WHERE TCNQ = TETRACYANOQUINODIMETHANE

被引：22

作者：

CECCONI, F

GHILARDI, CA

MIDOLLINI, S

ORLANDINI, A

机构：

[1] Istituto per lo Studio della Stereochimica ed Energetica dei Composti di Coordinazione, CNR, 50132 Florence

来源：

INORGANICA CHIMICA ACTA | 1993年 / 214卷 / 1-2期

关键词：

D O I：

10.1016/S0020-1693(00)87518-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unprecedented double stellated octahedral cluster [Co12(mu3-S)14(mu4-S)2(PEt3)10][TCNQ]2, has been isolated and characterized by an X-ray structure determination. The cation contains two stellated octahedral Co6S8 cores linked together through two mu4-S bridging ligands. The tetracyanoquinodimethane anion exists as the [TCNQ]22- diner, exhibiting the ring-over exocyclic bond type overlap.

引用

页码：13 / 15

页数：3

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