STEREOCONTROLLED RADICAL REACTIONS IN CARBOHYDRATE AND NUCLEOSIDE CHEMISTRY

被引：31
作者：
BARTON, DHR
GERO, SD
QUICLETSIRE, B
SAMADI, M
机构：
[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE
[2] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843
来源：
TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 11期
关键词：
D O I：
10.1016/S0957-4166(00)86288-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The radicals, generated by photolysis of 2,3-dimethyl ketals of N-hydroxy-2- thiopyridone uronic esters, reacted stereoselectively with electron deficient olefins leading to highly functionalised chain-elongated pentafuranosides, hexapyranosides and pentafuranosyl-nucleosides through the 4,5 and 4' radicals, respectively.
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页码：2123 / 2136
页数：14
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