Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine

被引:2
作者
Thirumurthy, Kannan [1 ]
Thirunarayanan, Ganesamoorthy [1 ]
Murugavel, S. [2 ]
机构
[1] Annamalai Univ, Dept Chem, Chidambaram 608002, Tamil Nadu, India
[2] Thanthai Periyar Govt Inst Technol, Dept Phys, Vellore 632002, Tamil Nadu, India
关键词
crystal structure; crystal packing; quinoline; carbazole; 9-ethyl-9H-carbazol-3-amine; C-H center dot center dot center dot pi interactions; pi-pi interactions;
D O I
10.1107/S2056989015005794
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)angstrom] and quinoline [maximum deviation = 0.050 (2) angstrom] ring systems form a dihedral angle of 50.2 (1)degrees. In the crystal, molecules are linked by C-H center dot center dot center dot pi and pi-pi interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) angstrom], forming a three-dimensional supramolecular network.
引用
收藏
页码:421 / +
页数:9
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