ENAMINOSULFONIUM SALTS .3. MORPHOLINO GROUP AS STEREOINDICATOR IN AMINOBICYCLO[4.1.0]HEPTANES

被引：37
作者：
VILSMAIER, E
TROGER, W
机构：
[1] Fachbereich Chemie der Universität, Kaiserslautern, D-6750, Paul-Ehrlich-Strasse
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 10期
关键词：
D O I：
10.1002/anie.197907981
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
exo/endo‐Assignment of aminobicyclo[4.1.0]heptanes (particularly with two bridging substituents) can be accomplished by means of the 1H‐NMR spectrum of the morpholino derivatives 1 and 2 (ABXY and AA′XX′ pattern of morpholine protons). The sequence below illustrates the new entry to these bicyclic species (X=morpholino, OH, OCH3; YOH, OCH3). (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany
引用
收藏
页码：798 / 800
页数：3
相关论文
共 10 条
[1]   CONJUGATED ENAMINES .3. SPECTROSCOPIC STRUCTURAL STUDIES OF CIS-FIXED, CYCLIC BETA ENAMINOESTERS WITH PARTICULAR CONSIDERATION OF INTERNAL HYDROGEN BRIDGES [J].
BLAZEJEWSKI, JC ;
CANTACUZENE, D ;
WAKSELMAN, C .
TETRAHEDRON, 1973, 29 (24) :4233-4239
[2]  
CAM PL, 1971, CHEM SCR, V1, P65
[3]  
CANTACUZENE D, 1971, TETRAHEDRON LETT, P4807
[4]   RING INVERSION IN MORPHOLINE AND PIPERAZINE DERIVATIVES STUDIED BY NUCLEAR MAGNETIC RESONANCE [J].
HARRIS, RK ;
SPRAGG, RA .
CHEMICAL COMMUNICATIONS, 1966, (10) :314-&
[5]  
SMUSZKOWICZ J, 1969, TETRAHEDRON LETT, P1309
[6]   NUCLEAR MAGNETIC RESONANCE STUDIES OF 6-MEMBERED RINGS .2. CHEMICAL SHIFTS AND COUPLING CONSTANTS IN MORPHOLINE AND PIPERAZINE DERIVATIVES [J].
SPRAGG, RA .
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1968, (10) :1128-&
[7]  
SZMUSZKOVICZ J, 1967, TETRAHEDRON LETT, P3969
[8]   SYNTHESIS AND THERMOLYSIS OF 2-AMINO-1-CYCLOALKENYLSULFONIUM SALTS [J].
VILSMAIER, E ;
TROGER, W ;
SPRUGEL, W ;
GAGEL, K .
CHEMISCHE BERICHTE-RECUEIL, 1979, 112 (08) :2997-3006
[9]  
WASSERMAN HH, 1976, J ORG CHEM, V41, P153, DOI 10.1021/jo00863a038
[10]  
WASSERMAN HH, 1971, TETRAHEDRON LETT, P3721
1