TRIPLE-DECKER TO METALLABENZENE - A NEW-GENERATION OF SANDWICH COMPLEXES

被引：43

作者：

BERTLING, U ^{[1
]}

ENGLERT, U ^{[1
]}

SALZER, A ^{[1
]}

机构：

[1] RHEIN WESTFAL TH AACHEN, INST ANORGAN CHEM, D-52056 AACHEN, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1002/anie.199410031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

How many more ways can three C5 ligands and two metal atoms be arranged? In addition to the classical triple‐decker A and the Cp‐bridged binuclear complex B, the first preparation of a metallabenzene sandwich complex of type C exemplifies a third structural isomer. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1003 / 1004

页数：2

共 25 条

[1]

[Anonymous], 1991, ANGEW CHEM, V103, P601

[2] TRANSITION-METAL NMR-SPECTROSCOPY .7. THE REACTIVITY OF COMPLEXED CARBOCYCLES .16. STRUCTURAL AND NMR SPECTROSCOPIC STUDIES OF CYCLOOCTATETRAENE AS A BRIDGING LIGAND - 5 DIFFERENT BONDING MODES IN DIMETALLIC COMPLEXES [J].

BIERI, JH ;

EGOLF, T ;

VONPHILIPSBORN, W ;

PIANTINI, U ;

PREWO, R ;

RUPPLI, U ;

SALZER, A .

ORGANOMETALLICS, 1986, 5 (12) :2413-2425

[3] METALLABENZENE CHEMISTRY [J].

BLEEKE, JR .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (09) :271-277

[4] GENERAL-ROUTE TO THE HALF-OPEN METALLOCENES C5ME5RU(PENTADIENYL) AND C5ME5RU(DIENE)CL - X-RAY STRUCTURES OF AN OPTICALLY-ACTIVE HALF-OPEN METALLOCENE AND OF A DIMETALLIC RUTHENABENZENE COMPLEX [J].

BOSCH, HW ;

HUND, HU ;

NIETLISPACH, D ;

SALZER, A .

ORGANOMETALLICS, 1992, 11 (06) :2087-2098

[5] METAL-PI-COMPLEXES OF HETEROARENES .3. BIS(ETA-6-PHOSPHABENZENE)VANADIUM - SYNTHESIS, STRUCTURE, REDOX PROPERTIES, AND CONFORMATIONAL FLEXIBILITY [J].

ELSCHENBROICH, C ;

NOWOTNY, M ;

METZ, B ;

MASSA, W ;

GRAULICH, J ;

BIEHLER, K ;

SAUER, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05) :547-550

[6]

ELSCHENBROICH C, 1992, ORGANOMETALLICS, P162

[7]

FRENZ BA, 1978, COMPUTING CRYSTALLOG

[8] PATHWAYS FOR CARBON CHAIN GROWTH REACTIONS AT A DIMOLYBDENUM CENTER [J].

GREEN, M ;

KALE, PA ;

MERCER, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (05) :375-377

[9] TRIPLE-DECKER COMPLEXES .9. TRIPLE-DECKER COMPLEXES WITH BRIDGING CYCLOPENTADIENYL LIGANDS AND NOVEL CYCLOPENTADIENYL TRANSFER-REACTIONS [J].

HERBERICH, GE ;

ENGLERT, U ;

MARKEN, F ;

HOFMANN, P .

ORGANOMETALLICS, 1993, 12 (10) :4039-4045

[10]

HERBERICH GE, 1993, J ORGANOMET CHEM, V458, P1

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