EFFECT OF WATER-VAPOR ON THE SELECTIVITY IN THE REDUCTION OF NITRIC-OXIDE WITH AMMONIA OVER VANADIA SUPPORTED ON SILICA TITANIA

被引：69
作者：
ODENBRAND, CUI
GABRIELSSON, PLT
BRANDIN, JGM
ANDERSSON, LAH
机构：
来源：
APPLIED CATALYSIS | 1991年 / 78卷 / 01期
关键词：
NITRIC OXIDE REDUCTION; VANADIA; TITANIA SILICA; NITROUS OXIDE; WATER; CRYSTALLINITY; SINTERING;
D O I：
10.1016/0166-9834(91)80092-B
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effect of the presence of water vapor on the reduction of nitric oxide with ammonia was investigated using vanadia on SiO2-TiO2 as a catalyst. The selectivity towards nitrogen is greatly increased upon addition of water. Repeated use at temperatures of 825 K causes sintering of the catalyst and loss of activity as well as selectivity towards nitrogen. The formation of nitrous oxide is preferentially taking place on large crystals of presumably reduced vanadia. Removal of these crystals results in a more selective catalyst.
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页码：109 / 123
页数：15
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