SYNTHESIS OF NEW HETEROCYCLES WITH DICOORDINATED PHOSPHORUS - 3-SUBSTITUTED THIAZOLO[3,2-D][1,4,2]DIAZAPHOSPHOLE AND ITS 5,6-DIHYDRO AND BENZO DERIVATIVES

被引：0

作者：

BANSAL, RK ^{[1
]}

MAHNOT, R ^{[1
]}

SHARMA, DC ^{[1
]}

KARAGHIOSOFF, K ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,W-8000 MUNICH 2,GERMANY

来源：

SYNTHESIS-STUTTGART | 1992年 / 03期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 3-substituted 2-aminothiazolium bromides 1-3 undergo cyclocondensation with phosphorus trichloride in acetonitrile in the presence of triethylamine to give the 3-substituted 5,6-dihydrothiazolo[3,2-d][1,4,2]diazaphospholes 4, thiazolo[3,2-d] [1,4,2]diazaphosphole 5 and its benzo derivatives 6. The products are characterized by P-31, H-1 and C-13 NMR spectra. Dimethyl sulfate alkylates 5 at N-7.

引用

页码：267 / 269

页数：3

共 7 条

[1] 2-PHOSPHAINDOLIZINES [J].

BANSAL, RK ;

KARAGHIOSOFF, K ;

GUPTA, N ;

SCHMIDPETER, A ;

SPINDLER, C .

CHEMISCHE BERICHTE, 1991, 124 (03) :475-480

[2] CHLOROMETHYL-DICHLOROPHOSPHANE - A USEFUL REAGENT FOR THE SYNTHESIS OF NEW HETEROCYCLES WITH DICOORDINATE PHOSPHORUS [J].

KARAGHIOSOFF, K ;

CLEVE, C ;

SCHMIDPETER, A .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1986, 28 (1-2) :289-296

[3] THE CHEMICAL-SHIFT OF .2. COORDINATE PHOSPHORUS .2. HETEROCYCLES [J].

KARAGHIOSOFF, K ;

SCHMIDPETER, A .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1988, 36 (3-4) :217-259

[4]

KARAGHIOSOFF K, 1990, MULTIPLE BONDS LOW C, P463

[5]

SCHMIDPETER A, 1985, NACHR CHEM TECH LAB, V33, P793

[6]

SCHMIDPETER A, 1989, RINGS CLUSTERS POLYM, P307

[7]

SCHMIDPETER A, 1990, MULTIPLE BONDS LOW C, P258

← 1 →