MOLECULAR RECTIFIER

被引：383

作者：

MARTIN, AS ^{[1
]}

SAMBLES, JR ^{[1
]}

ASHWELL, GJ ^{[1
]}

机构：

[1] CRANFIELD INST TECHNOL,CTR MOLEC ELECTR,CRANFIELD MK43 0AL,BEDS,ENGLAND

来源：

PHYSICAL REVIEW LETTERS | 1993年 / 70卷 / 02期

关键词：

D O I：

10.1103/PhysRevLett.70.218

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Current density-voltage characteristics are presented for a molecular structure of the form metal/organic-multilayer/metal for which the rectifierlike forward bias current density dependence is unequivocally associated with zwitterionic molecules. By placing passive organic barriers between the metal layers and the active molecules we prove that Schottky barrier effects are not important. This is the clearest evidence so far for molecularly controlled rectification, the basis for molecular electronics.

引用

页码：218 / 221

页数：4

共 17 条

[1] PHOTOCHROMIC AND NONLINEAR OPTICAL-PROPERTIES OF C16H33-P3CNQ AND C16H33-Q3CNQ LANGMUIR-BLODGETT-FILMS [J].

ASHWELL, GJ .

THIN SOLID FILMS, 1990, 186 (01) :155-165

[2] LANGMUIR-BLODGETT ALIGNMENT OF ZWITTERIONIC OPTICALLY NONLINEAR D-PI-A MATERIALS [J].

ASHWELL, GJ ;

DAWNAY, EJC ;

KUCZYNSKI, AP ;

SZABLEWSKI, M ;

SANDY, IM ;

BRYCE, MR ;

GRAINGER, AM ;

HASAN, M .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (07) :1117-1121

[3]

ASHWELL GJ, 1990, Patent No. 90072307

[4]

ASHWELL GJ, 1990, Patent No. 84760

[5]

ASHWELL GJ, 1990, J CHEM SOC CHEM COMM, V19, P1374

[6]

ASHWELL GJ, 1990, Patent No. 903034734

[7]

ASHWELL GJ, 1990, J CHEM SOC CHEM COMM, V19, P1355

[8] MOLECULAR RECTIFIERS [J].

AVIRAM, A ;

RATNER, MA .

CHEMICAL PHYSICS LETTERS, 1974, 29 (02) :277-283

[9] MOLECULAR ELECTRONICS [J].

BLOOR, D .

PHYSICA SCRIPTA, 1991, T39 :380-385

[10] THERMALLY STIMULATED CURRENTS IN FATTY-ACID LANGMUIR-BLODGETT FILMS SANDWICHED BETWEEN METAL-ELECTRODES [J].

GEDDES, NJ ;

SAMBLES, JR ;

COUCH, NR ;

PARKER, WG ;

JARVIS, DJ .

THIN SOLID FILMS, 1989, 179 :143-153

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