SYNTHESIS AND STRUCTURE OF A RAC-TRIS(DIVINYLDISILOXANE)DIPLATINUM(0) COMPLEX AND ITS REACTION WITH MALEIC-ANHYDRIDE

被引：184

作者：

HITCHCOCK, PB ^{[1
]}

LAPPERT, MF ^{[1
]}

WARHURST, NJW ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 04期

关键词：

D O I：

10.1002/anie.199104381

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

rac-Tris(divinyldisiloxane)diplatinum(0) 1 is obtained on reaction of [Pt(cod)2] with tetramethyldivinyldisiloxane. Detailed multinuclear NMR studies showed that solutions of 1 are almost identical to the catalytically active solution which is used in the hydrosilation of unsaturated compounds.

引用

页码：438 / 440

页数：3

共 10 条

[1] A CONVENIENT AND NOVEL ROUTE TO BIS(ETA-ALKYNE)PLATINUM(0) AND OTHER PLATINUM(0) COMPLEXES FROM SPEIER HYDROSILYLATION CATALYST H2[PTCL6].XH2O - X-RAY STRUCTURE OF [PT((ETA-CH2=CHSIME2)2O)(P-TERT-BU3)] [J].

CHANDRA, G ;

LO, PY ;

HITCHCOCK, PB ;

LAPPERT, MF .

ORGANOMETALLICS, 1987, 6 (01) :191-192

[2] FUMARATE, MALEATE AND MALEIC-ANHYDRIDE COMPLEXES OF PLATINUM(O) [J].

CHICOTE, MT ;

GREEN, M ;

SPENCER, JL ;

GORDON, F ;

STONE, A ;

VICENTE, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 137 (01) :C8-C10

[3]

CUNDY CS, 1973, ADV ORGANOMET CHEM, V11, P330

[4] SYNTHESIS OF ETHYLENE, CYCLO-OCTA-1,5-DIENE, BICYCLO[2.2.1]HEPTENE, AND TRANS-CYCLO-OCTENE COMPLEXES OF PALLADIUM(0) AND PLATINUM(0) - CRYSTAL AND MOLECULAR-STRUCTURE OF "TRIS(BICYCLO[2.2.1]HEPTENE)PLATINUM [J].

GREEN, M ;

HOWARD, JAK ;

SPENCER, JL ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (03) :271-277

[5] X-RAY AND NEUTRON-DIFFRACTION STUDIES OF THE CRYSTAL AND MOLECULAR-STRUCTURES OF TRIS(ETHYLENE)PLATINUM AND BIS(ETHYLENE)(TETRAFLUOROETHYLENE)PLATINUM [J].

HOWARD, JAK ;

SPENCER, JL ;

MASON, SA .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1983, 386 (1790) :145-161

[6] BIS(1,5-CYCLOOCTADIENE)PLATINUM(O) - X-RAY STRUCTURE AT 200-K [J].

HOWARD, JAK .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (NOV) :2896-2898

[7]

Speier J.L., 1979, ADV ORGANOMET CHE, V17, P407, DOI [10.1016/S0065-3055(08)60328-7, DOI 10.1016/S0065-3055(08)60328-7]

[8]

Stark F. O., 1982, COMPR ORGANOMET CHEM, P305

[9]

WARHURST NJW, 1990, THESIS U SUSSEX

[10]

WILLING DN, 1968, Patent No. 3419593

← 1 →