A DOUBLY BRIDGED BINUCLEAR IRON(III) COMPLEX CONTAINING INEQUIVALENT METAL ENVIRONMENTS - SYNTHESIS, STRUCTURE AND MAGNETISM

被引：39

作者：

FALLON, GD

MARKIEWICZ, A

MURRAY, KS

QUACH, T

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[2] MONASH UNIV,COLL GIPPSLAND,SCH APPL SCI,GIPPSLAND,VIC 3842,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 03期

关键词：

D O I：

10.1039/c39910000198

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New doubly bridged iron(III) complexes [Fe2(L(A)(OMe)(Cl)2MeOH] 1 and [Fe2(L(B))(OH)Cl2] 2, have been synthesized using the binucleating ligands H3L(A) = N,N'-bissalicylidene-1, 3-diaminopropan-2-ol) and H3L(B) = N,N'-bissalicylideneimine-1,5-diaminopentan-3-ol; the crystal structure of 1 shows inequivalent coordination environments, a feature which is relevant to Fe geometries in iron-oxo proteins, and 1 shows an intramolecular antiferromagnetic J value of - 10.6 cm-1.

引用

页码：198 / 200

页数：3

共 25 条

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