FTIR STUDIES OF THE REACTION OF O(D-1)-ATOMS WITH CF3BR IN SOLID ARGON MATRICES

被引：7

作者：

LORENZENSCHMIDT, H

WELLER, R

SCHREMS, O

机构：

[1] Alfred-Wegener-Institute for Polar-and Marine Research, Chemistry Section, Bremerhaven

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1995年 / 349卷

关键词：

D O I：

10.1016/0022-2860(95)08777-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction O(D-1) + CF3Br has been investigated in solid Ar-matrices at T=14 K. Codeposition of O-3/CF3Br/Ar mixtures and irradiation at 250 nm yielded F2CO as dominant reaction product. Experiments with O-18(3) indicate that CF3OBr was formed during the course of the reaction. Our observations were interpreted with the formation of an excited CF3OBr molecule which can be stabilized in the matrix cage or decompose rapidly into two different F2CO . HF complexes.

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页码：333 / 336

页数：4

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