ENZYME-CATALYZED CONDENSATION POLYMERIZATION OF 11-HYDROXYUNDECANOIC ACID WITH LIPASE FROM CANDIDA-CYLINDRACEA

被引：38

作者：

OHAGAN, D

ZAIDI, NA

机构：

[1] Department of Chemistry, Science Laboratories, University of Durham, Durham, DH1 3LE, South Road

来源：

POLYMER | 1994年 / 35卷 / 16期

关键词：

CONDENSATION POLYMERIZATION; LIPASE; 11-HYDROXYUNDECANOIC ACID;

D O I：

10.1016/0032-3861(94)90928-8

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The enzyme-catalysed condensation polymerization of 11-hydroxyundecanoic acid in hexane with the lipase from Candida cylindracea is reported. Molecular weights up to 35000 are attained. A time course study of the polymerization process reveals that oligomers are formed relatively rapidly and that these oligomers then condense to generate higher molecular weight polyesters.

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页码：3576 / 3578

页数：3

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