POSITRON-ANNIHILATION STUDY IN POLYANILINE CONDUCTING POLYMER

被引:7
作者
PENG, ZL [1 ]
LI, SQ [1 ]
DAI, YQ [1 ]
WANG, B [1 ]
WANG, SJ [1 ]
LIU, H [1 ]
XIE, HQ [1 ]
机构
[1] HUAZHONG UNIV SCI & TECHNOL,DEPT CHEM,WUSHAN 430072,PEOPLES R CHINA
来源
JOURNAL DE PHYSIQUE IV | 1993年 / 3卷 / C4期
关键词
D O I
10.1051/jp4:1993438
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The positron lifetime spectra in polyaniline have been measured as a function of protonation level (pH from 7 to -0.8) . We observed that (1) the short lifetime tau1 decreased with the protonation level; (2) the intermediate lifetime was constant (tau2 almost-equal-to 360 ps), whereas its intensity I2 increased with increasing protonation level which was related to the conductivity of material. These results are discussed in terms of conducting island model.
引用
收藏
页码:253 / 255
页数:3
相关论文
共 5 条
[1]   POLYANILINE - PROTONIC ACID DOPING OF THE EMERALDINE FORM TO THE METALLIC REGIME [J].
CHIANG, JC ;
MACDIARMID, AG .
SYNTHETIC METALS, 1986, 13 (1-3) :193-205
[2]   PROTONATION OF EMERALDINE - FORMATION OF A GRANULAR POLARONIC POLYMERIC METAL [J].
EPSTEIN, AJ ;
MACDIARMID, AG .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 160 :165-173
[3]   POSITRONFIT EXTENDED - NEW VERSION OF A PROGRAM FOR ANALYZING POSITRON LIFETIME SPECTRA [J].
KIRKEGAARD, P ;
ELDRUP, M .
COMPUTER PHYSICS COMMUNICATIONS, 1974, 7 (07) :401-409
[4]   POSITRON-ANNIHILATION AND CONDUCTIVITY MEASUREMENTS ON POLY(PYRROLE TOSYLATE) AND POLY(PYRROLE FLUORIDE) [J].
SHARMA, SC ;
KRISHNAMOORTHY, S ;
NAIDU, SV ;
EOM, CI ;
KRICHENE, S ;
REYNOLDS, JR .
PHYSICAL REVIEW B, 1990, 41 (08) :5258-5265
[5]   TRANSPORT STUDIES OF PROTONATED EMERALDINE POLYMER - A ANTIGRANULOCYTES POLYMERIC METAL SYSTEM [J].
ZUO, F ;
ANGELOPOULOS, M ;
MACDIARMID, AG ;
EPSTEIN, AJ .
PHYSICAL REVIEW B, 1987, 36 (06) :3475-3478