REEXAMINATION OF THE THERMOLYTIC REARRANGEMENT OF 4-HALOPHENYL AZIDES TO 2-AMINOPHENOLS AND OTHER PRODUCTS

被引：23

作者：

GERSHON, H ^{[1
]}

CLARKE, DD ^{[1
]}

GERSHON, M ^{[1
]}

机构：

[1] NEW YORK BOT GARDEN, BRONX, NY 10458 USA

来源：

MONATSHEFTE FUR CHEMIE | 1993年 / 124卷 / 04期

关键词：

ACETYLATED-2-AMINO-5-HALOPHENOLS; 2-ACETAMIDO-5-HALOANISOLES; 6-HALO-2-METHYLBENZOXAZOLES; 6-HALOBENZOXAZOLONES; 6-HALOTRIACETYLAMINOPHENOLS; H-1-NMR SPECTRA; FUNGICIDAL ACTIVITY;

D O I：

10.1007/BF00814133

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The halogenation of derivatives of 2-aminophenol with N-chloro- and N-bromosuccinimides at ambient temperatures in acetic acid was studied. With the necessary compounds available, a reexamination of the thermolytic rearrangement of 2-halophenyl azides to 2-aminophenols and other products was undertaken. It is certain that the rearrangement of 4-halophenyl azides to 2-aminophenols occurs but the products identified in this study differ significantly from those reported previously by Suschitzky et al. (1963, 1966).

引用

页码：367 / 379

页数：13

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