THE ORANGE BAND SYSTEM OF SRO - 1ST DETAILS ABOUT THE TRIPLET TRANSITIONS

被引：7

作者：

HERRMANN, RFW ^{[1
]}

SUMNICHT, GK ^{[1
]}

STEIN, M ^{[1
]}

ERNST, WE ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST EXPTL PHYS,W-1000 BERLIN 33,GERMANY

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1992年 / 156卷 / 02期

关键词：

D O I：

10.1016/0022-2852(92)90248-M

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The laser spectroscopic study of the orange band system of SrO near 596 nm is presented. Two 3Π-3Π transitions are identified, the lower state being a3Π (v = 0) in both cases. The previously unknown upper states are named f3Π and g3Π. Fluorescence from f- and g-state levels to the X1Σ+ ground state and a new 3Σ+ state (called b3Σ+) are assigned. Perturbations are observed in the g3Π2-a3Π2 (0, 0) band. Spectroscopic constants are determined in a combined fit of the measured f-a, g-a, f-b, g-b, f-X, and g-X transitions. The main parameters are (in cm-1): {A table is presented} Standard errors are in parentheses. © 1992.

引用

页码：487 / 500

页数：14

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