KINETICS OF RADICAL POLYMERIZATION OF DIMETHYLPHENYL METHACRYLATES

被引：2
|
作者：
VRHOVAC, L [1 ]
DJURASOVIC, N [1 ]
VELICKOVIC, J [1 ]
机构：
[1] UNIV BELGRADE, FAC TECHNOL & MET, KARNEGIJEVA 4, POB 494, YU-11000 BELGRADE, YUGOSLAVIA
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1993年 / 31卷 / 01期
关键词：
FREE RADICAL POLYMERIZATION; DIMETHYLPHENYL METHACRYLATES; KINETICS; DILATOMETRY; DIPOLES INTERACTION;
D O I：
10.1002/pola.1993.080310105
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The kinetics of free radical polymerization of all six existing isomeric dimethylphenyl methacrylates were studied in bulk at 60-degrees-C, initiated by dilauroyl peroxide, using dilatometry. The different polymerization rates observed, resulting from the different monomer structures, are discussed in terms of steric and other effects, considering also the previous results for tolyl methacrylates.
引用
收藏
页码：45 / 50
页数：6
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