Temperature dependence of spontaneous polarization P(s)(T) in ferroelectric Li2Ge7O15 crystals has been measured in a wide range of temperature from 300 K to 15 K by a pyroelectric charge method. Temperature dependence of dielectric constant epsilon (T) has precisely been measured in the paraelectric phase. It is shown that the experimental results can be explained by a ferrielectric model, in which two kinds of nonequivalent antiparallel sublattice polarizations are induced by a soft phonon mode having negligibly small oscillator strength.
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页码:297 / 302
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BUSH AA, 1986, SOV PHYS-SOLID STATE, V28, P1101